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How to detect ceramic composition analysis?

Date:2024-07-08 09:42:13 Classification :【question】 Visits:
Ceramic composition analysis is a complex and delicate process that aims to gain insight into the ceramic's raw material composition, firing process and possible defects. The following are some commonly used ceramic composition analysis methods:

1. Chemical analysis method

1. Specific gravity method:

By mixing ceramic powder with a high-boiling point liquid, the oxides are dissolved and the powder precipitates, thereby measuring the specific gravity of various oxides in the ceramic.

This method, while accurate, often requires destructive processing of the sample, such as breaking the ceramic into powder.

2. Acid-base titration method:

It is mainly used to determine the content of alkaline earth metal oxides such as Mg, Ca, Ba, etc. in ceramic materials.

Based on the chemical reaction of weak acid and weak base, the content in the sample is calculated by titrating the amount of acid and alkali.

2. Physical analysis method

1. X-ray diffraction (XRD):

It is a very effective physical analysis method that can quickly and accurately analyze the crystal structure and composition of ceramic materials.

By irradiating the ceramic sample with X-rays, the diffraction pattern of the sample is obtained, and then the crystal structure, unit cell parameters, and content of each element in the ceramic are analyzed.

It is non-destructive, fast and accurate, and has been widely used in ceramic composition analysis and detection.

2. Infrared spectrum analysis:

Analyze the composition and structure of ceramic materials based on the vibration frequencies of chemical bonds in them.

This method has high sensitivity and resolution and is of great significance for the analysis of complex ceramic components.

3. Raman spectrum analysis:

Information on the composition of the ceramic is obtained by measuring the scattering spectra of the molecules in the ceramic.

It is also non-destructive and has unique advantages for the detection of specific components.


3. Other analysis methods

1. Scanning electron microscope (SEM):

By scanning the electron beam to irradiate the surface of the material, the surface morphology and microstructure of the sample are observed to analyze the composition and structure of the sample.

2. Atomic absorption spectrometry (AAS):

It is a highly sensitive analytical method that can be used to determine the content of metal elements in ceramics.

3. Differential Thermal Analysis (DTA):

Analyze the composition and structure of a sample by measuring the temperature difference during heating or cooling.

4. Special methods for ancient ceramics

For ceramic artifacts with special value such as ancient ceramics, non-destructive testing technology is particularly important. The following are some compositional analysis methods applicable to ancient ceramics:

1. Energy X-ray Fluorescence Analysis (EDXRF):

A simple and commonly used non-destructive in-situ measurement method quantitatively determines the composition and content of major and trace chemical components in porcelain bodies, enamel glazes and pigments, and compares them with traceable corresponding standard sample data to achieve traceability and dating.

2. Proton excited X-fluorescence analysis (PIXE):

The sensitivity is higher than EDXRF, it can be both lossy and non-destructive, and it is suitable for in-depth analysis of ancient ceramics.

3. Synchrotron radiation X-ray fluorescence analysis (SRXRF):

Using synchrotron radiation X-rays as the excitation source, the types and contents of elements in ancient ceramics were analyzed. However, since porcelain will produce long-lived radionuclides after being irradiated by neutrons, it is not suitable for testing ancient folk ceramic collections.


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